Abstract:TiN composite coatings were successfully fabricated on 45 steel surface using commercial pure titanium powders by means of reactive plasma spraying technology. The phase composition of the coating was analyzed with XRD. The microstructure, indentation, fracture and worn morphologies of TiN coating were observed through SEM. The indentation composition was analyzed by EDS. The micro-hardness and the wear resistance were also determined as well. Results indicate that the coating is mainly consisted of TiN, TiN0.3 and Ti3O. The coating has typical layer structure, and the layers between coatings or substrates are in good adhesive condition. The micro-hardness of the coating is 983-1 254 HV0.1. The indentation is clear and there is no crack around. The fracture morphology shows that the coating has better toughness and the fracture mechanism is a mixture of ceramic and ductile materials. The coating has the best wear resistance when the load is low.
[1]薛小锋, 王泽华, 周泽华, 等.熔铸法制备金属复合涂层微观组织的研究[J].粉末冶金工业, 2015, 25(2):39-45
[2]E.E.Vera,MVite,R.Lewis,et al. A study of the wear performance of TiN,CrN and WCC coatings on different steel substrates[J].Wear, 2011, 271(9-10):2116-2124
[3]Borgioli F, Galvanetto E, Galliano F P, et al.Sliding wear resistance of reactive plasma sprayed Ti-TiN coatings[J].Wear, 2006, 260(7-8):832-837
[4]Viorel-Aurel Serban, Radu Alexandru Rosu, Alexandra Ioana Bucur, et al.Deposition of titanium nitride layers by electric arc-Reactive plasma spraying method[J].Applied Surface Science, 2013, 265(15):245-249
[5]赵雪勃, 阎殿然, 董艳春, 等.反应等离子喷涂涂层热处理后的电化学腐蚀性能[J].材料热处理学报, 2012, 33(4):121-126
[6]S.H.Kim,HPark,K.H.Lee,et al.Structure and mechanical properties of titanium nitride thin films grown by reactive pulsed laser deposition[J].Journal of Ceramic Processing Research, 2009, 10(1):49-53
[7]L.Xiao,DYan,J.He,et al.Nanostructured TiN coating prepared by reactive plasma spraying in atmosphere[J].Applied Surface Science, 2007, 253(18):7535-7539
[8]H.Tahara,YAndo.Study of titanium nitride deposition by supersonic plasma spraying[J].Vacuum, 2009, 83(1):98-101
[9]闫华, 王爱华, 熊钊颋, 等.自蔓延反应喷涂技术最新研究及进展[J].材料导报, 2009, 23(7):91-104
[10]王泽华, 王长浩, 周泽华等.高温反应合成金属-陶瓷复合涂层技术的研究现状[J].表面技术, 2012, 41(3):115-119
[11]Liang X, Sickinger A, Wolfenstine J, et al.In-situ carburized coating produced by reactive plasma spraying of low carbon steel using methane[J].Materials Science and Engineering, 1996, 212(1):51-61
[12] 姚燚红.气相反应等离子喷涂TiN涂层及性能研究[D].南京:河海大学, 2012.
[13]成志芳, 马壮, 卢林.等离子喷涂-%涂层微观组织形貌分析[J].表面技术, 2012, 41(3):9-11
[14]邹东利, 阎殿然, 何继宁, 等.反应等离子喷涂复相陶瓷涂层[J].材料科学与工程学报, 2007, 25(4):593-597
[15]Xie Guozhi, Song Xiaolong, Zhang Dongjie et al.Microstructure and corrosion properties of thick WC composite coating formed by plasma cladding[J].Applied Surface Science, 2010, 256(21):6354-6358
[16]V.BuscagliaDecomposition of Al2TiO5 and Al2(1-x)MgxTi(1+x)O5 ceramics[J].Journal of The American Ceramic Society, 1998, 81(10):2645-2653
[17]J.J.Zhang,ZH.Wang,P.H.Lin,et al. Effect of Vacuum Annealing on the Characteristic of Plasma Sprayed Al2O3-13wt% TiO2 Coatings[J].Journal of Thermal Spray Technology, 2012, 21(5):782-791
[18]王黎明, 胡梅.粉末烧结层的组织与性能研究[J].粉末冶金工业, 2015, 25(3):44-50