Abstract:The oxidation kinetics curve and oxidation rate of sintered nickel-based superalloy mesh porous materials with two different sizes and dense monofilament samples at 900 ℃ were tested through static weight gain method. The surface area of the porous small sample was tested through the 9410 automatic mercury porosimeter, and was also calculated through the permeability coefficient, and the oxidation rate of the porous small sample was corrected accordingly. The morphology and oxide composition of the porous samples were observed by SEM, EDS and XRD. The results show that the oxidation rate of the large and small porous samples is about 7 times that of monofilament sample after 100 h oxidation experiment. The oxidation rate of the modified small porous sample is much smaller than that before being corrected, which is also smaller than the oxidation rate of the monofilament sample. The surface oxide of the porous samples is spherical and distributed uniformly, and its composition is mainly NiCr2O4.
[1]Chen J H.Rogers P MLittle J A. Oxidation behavior of several chromia-forming commercial nickel-base superalloys[J].Oxid.Met., 1997, 49(56):381-410
[2]Guofeng Chen, Hanyi Lou.Effect of Nanocrystallization on the Oxidation Behavior of a Ni-8Cr-35Al Alloy[J].Oxidation of Metals., 2000, 54(1):155-162
[3]赵双群,董建新,张麦仓,等.新型镍基高温合金在℃和℃的氧化行为[J].稀有金属材料与工程, 2005, 34(2):208-211
[4]王会阳,安云岐,李承宇,等.镍基高温合金材料的研究进展[J].材料导报, 2011, 25(18):482-486
[5] 方玉诚,王浩,周勇,等.粉末冶金多孔材料新型制备与应用技术的探讨[J][J].稀有金属, 2005, 29(5):791-796
[6]乔吉超,奚正平,汤慧萍,等.粉末冶金技术制备金属多孔材料研究进展[J].稀有金属材料与工程, 2008, 37(11):2054-2058
[7]Peukert W.High temperature filtration in the process industry[J].Filtration & Separation., 1998, 35(5):461-464
[8]Chen M F, Douglass D L, GESMUNDO F.High-temperature sulfidation behavior of Ni-Nb alloys[J].Oxidation of Metal, 1989, 31(34):237-263
[9] 杨富民,黎用启译.多孔介质[M]. 北京:石油工业出版社,1990.47-51
[10] 江宏俊.流体力学[M]. 北京:高等教育出版社,1985.235-238