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| Study on the morphology and application properties of small particle size nickel-manganese binary precursor Ni0.6Mn0.4(OH)2 |
| YANG Yongsheng，LIU Fei，SUN Lei，LIU Jiying，MI Xixue，WANG Yaoxi |
| （Ningxia zhongse New Material Co., Ltd., Shizuishan 753000, China） |
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Abstract The development of low cobalt or cobalt-free ternary precursor materials is of great significance for the
development of low cost and high energy density ternary lithium electric materials. In recent years, due to the longterm high price of cobalt salt, it has become a constraint on the development of new energy vehicles. Among them,
medium/high nickel or lithium rich manganese based cathode materials have attracted widespread attention. The
electrochemical performance of cathode materials based on lithium batteries largely depends on the performance of
precursors. It is particularly important to study the effects of ammonia concentration, pH value, nucleation method,
and reaction temperature on surface morphology by preparing low cobalt or cobalt free precursors. The precursor
material Ni
0.6Mn0.4(OH)2 was prepared by coprecipitation controlled crystallization method with nickel sulfate and
manganese sulfate as raw materials. During the preparation process, the effects of ammonia concentration, pH val‐
ue, nucleation method, and reaction temperature on the morphology of the product were mainly investigated. The
effects of ammonia concentration, pH value, nucleation mode and reaction temperature on the surface morphology
of the precursor were characterized by SEM and EDS. The effects of different ammonia concentrations on the phys‐
ical and chemical indicators of the material were characterized by carbon sulfur analyzer, tap density tester, and
BET. The effect of different ammonia concentrations on the electrochemical performance of positive electrode ma‐
terials was characterized through electrochemical testing. The results show that when the ammonia concentration
increases from 0 mol/L to 0.14 mol/L, the primary particles of the precursor grow gradually from filamentation to
transverse broadening, and the increase of ammonia concentration is conducive to the preparation of low-sulfur and
dispersive precursor. The influence of pH value on the surface morphology of precursors is mainly manifested in the nucleation rate and growth rate of precursors, as well as the degree of primary particle thickness. High pH val‐
ues prioritize nucleation with growth as a secondary factor, while low pH values have the opposite effect. Com‐
pared to the above two influencing factors, the nucleation method mainly affects the sphericity of the precursor and
the core structure of the precursor. The nucleation method using nickel cobalt manganese solution, ammonia solu‐
tion, and sodium hydroxide solution simultaneously has poor sphericity, but high capacity and poor circulation.
However, the nucleation method using nickel sodium solution simultaneously has high sphericity of the precursor,
and good capacity and circulation of the positive electrode material. The reaction temperature mainly affects the
thickness and sphericity of the precursor primary particles. The higher the temperature, the thicker the primary par‐
ticles, and the worse the sphericity. Finally, the ammonia concentration is determined to be 0.14 mol/L, with pH
ranging from 11.5 to 11.6. The nucleation method uses nickel solution and sodium hydroxide solution simultane‐
ously to prepare precursor Ni0.6Mn0.4(OH)2 with good morphology and excellent electrochemical performance as the
cathode material. The results show that the precursor products with excellent performance can be prepared only
when the appropriate ammonia concentration matches the appropriate reaction pH value, nucleation method and re‐
action temperature.
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Received: 03 January 2023
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Corresponding Authors:
刘 飞（1976—），男，学士，高级工程师，主要研究方向为锂离子电池正极材料。
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2024, Vol. 34 
