Abstract:L10 structured (FePt)1-x Cux nanoparticles (NPs) were directly prepared by polyol method at 340 ℃. The effects of copper additive on the morphology, structure and chemical ordering of as-prepared FePt NPs were investigated. X ray diffraction results showed that without Cu doping the as-prepared NPs possessed fcc structure and gradually showed typical fct diffraction peaks after increasing the Cu doping concentration. Meanwhile the metallic Cu phase is observed. TEM images exhibited that as-prepared NPs had bigger particles size and wider particle size distribution after introducing Cu additive. Magnetic properties measurement showed that a coercivity of 1300 Oe was obtained when the molar ratio of Cu reached 25. 9% in the (FePt)1-xCux nanoparticles. This study indicated Cu doping has a certain in promoting the phase-transition of FePt nanoparticles.
穆钰平,汪汉斌,刘向,张军,王浩. 铜掺杂一步合成fct结构FePt纳米颗粒[J]. , 2014, 21(1): 12-16.
MU Yu-ping, WANG Han-bin, LIU Xiang, ZHANG Jun, WANG Hao. One-Step Preparation of fct-Structure FePt Nanoparticles by Doping Cu. , 2014, 21(1): 12-16.
KIM J, RONG C B, LIU J P, et al.Dispersible Ferromagnetic FePt Nanoparticles[J].Adv. Mater, 2009, 21(8):906-909
[5]
HIROAKI K, TETSUYA S, MIGAKU T, et al.Effect of Coalescence on Ordering and c-Axis Orientation of FePt,FePtAu,and FePtCu Nanoparticles Heat-Treated in Magnetic Field[J].J. Appl. Phys, 2008, 47(5):3466-
[7]
PINHO S L C, LAURENT S, ROCHA J, et al.Relaxometric Studies of γ-Fe2O3@SiO2 Core Shell Nanoparticles: When the Coating Matters[J].J. Phys. Chem. C, 2012, 116(3):2285-2291
[8]
Lee D C, Mikulec F V, Pelaez J M, et al.Synthesis and Magnetic Properties of Silica-Coated FePt Nanocrystals[J].J. Phys. Chem. B, 2006, 110(23):11160-11166
CAPOBIANCHI A, COLAPIETRO M, FIORANI D, et al.General Strategy for Direct Synthesis of L10 Nanoparticle Alloys from Layered Precursor: The Case of FePt[J].Chem. Mater, 2009, 21(10):2007-2009
[11]
SORT J, SURINACH S, DOLORS B M, et al.Direct Synthesis of Isolated L10 FePt Nanoparticles in a Robust TiO2 Matrix via a Combined Sol–GelPyrolysis RouteAdv[J].Adv. Mater, 2006, 18(4):466-470
[13]
YANG F J, WANG H, WANG B Y, et al.Thickness dependence of microstructure and magneic properties in FePtB4C multilayer thin films[J].Appl. Phys. A, 2009, 94(4):981-985
[15]
JIA Z Y, KANG S S, NIKLES D E, et al.Synthesis of FePtAu nanoparticles in high-boiling- point solvents[J].IEEE Trans. Mag, 2005, 41(10):3385-3387
[17]
GAO Y, ZHANG X W, QU S, et al.Reduction of Ordering Temperature of Self-Assembled FePt Nanoparticles articles by Addition of Au and Ag[J].Nanosci. Nanotechnol, 2011, 11(12):10548-10552
[18]
CHEPULSKII, ROMAN V.First principles study of Ag,Au,and Cu surface segregation in FePt-L10[J].Appl. Phys. Lett, 2010, 97(22):221908-221908
[20]
WANG H B, SHANG P J, ZHANG J, et al.One-step synthesis of high-coercivity L10-FePtAg nanoparticles: effects of Ag on the morphology and chemical ordering of FePt nanoparticles[J].Chemistry of Materials, 2013, 25(12):2450-2454
[21]
BERRY D C, KIM J, BARMAK K, et al.Differential scanning calorimetry studies of the effect of Cu on the A1 to L10 transformation in FePt thin films[J].Scripta Materialia, 2005, 53(4):423-428
[23]
WANG L W, KLEMMER, TIMOTHY J, et al.Tuning magnetic anisotropy in (001) oriented L10 (Fe1-xCux)55 Pt45 films[J].Appl. Phys Lett, 2013, 102(13):132406-132406
[24]
WANG H X, LI M, ZHANG L D, et al.Structural and magnetic properties of (FePt)1-xCux nanowires[J].ScienceDirect. Phys E, 2010, 42(5):1393-1396
[1]
WELLER D, MOSER A, FOLKS L.High Kμ materials approach to 100Gbitsin2[J].IEEE Trans Magn, 2000, 36(1):10-12
TAMADA Y, YAMAMOTO S, NASU S, et al.Structural and magnetic properties of L10-FePt nanoparticles aligned by external magnetic field[J].Phy. Rev. B, 2008, 78(21):214428-
[9]
DONG A G.CHEN J,YE X C,et alEnhanced Thermal Stability and Magnetic Properties in NaCl-Type FePt–MnO Binary Nanocrystal Superlattices[J].J. Am. Chem. Soc, 2011, 133(34):13296-13299
[12]
LI D, POUDYAL N, NANDWANA V, et al.Hard magnetic FePt nanoparticles by salt-matrix annealing[J].Appl. Phys, 2006, 99(8):08-E911
[14]
CHEPULSKII, ROMAN V.First principles study of Ag,Au,and Cu surface segregation in FePt-L10[J].Appl. Phys. Lett, 2010, 97(22):221908-221908
[16]
ZAFIROPOULOU I, DEVLIN E, BOUKOUS N, et al.Direct Chemical Synthesis of L10 FePt Nanostructures[J].Chem. Mater, 2007, 19(8):1898-1900
[19]
HIROTSH Y, RYU H W, SATO K, et al.Electron microscopy study of L10-FePtCu nanoparticles synthesized at 613K[J].Journal of Microscopy, 2009, 236(2):94-99
[22]
WIERMAN K W, PLATT C L, HOWARD J K.Impact of stoichiometry on L10 ordering in FePt and FePtCu thin films[J].Journal of Magnetism and Magnetic Materials, 2004, 278(1-2):214-217
[25]
SUN S H, MURRAY C B, WELLER D, et al.Monodisperse FePt Nanoparticles and Ferromagnetic FePt Nanocrystal Superlattices[J].Science, 2000, 287(5460):1989-1992