Abstract:Titanium (Ti) and its alloys have become the preferable high-load bone substitute materials and successfully been used in medical implants due to their good biomechanical and biochemical properties. However, the elastic modulus of Ti and its alloys are not matched with bones tissue and may result in so called "stress-shielding". Hydroxyapatite (HA) is the main ingredient of natural bone mineral substance, so that it has excellent bioactivity and biocompatibility. But its application is limited because of the low strength, brittleness, and worse load-carrying capacity. Based on researches of preparation and the fundamental property of Ti-HA composites,present progress of Ti-HA composites reinforced by various nano-materials and doped by rare earth element were summarized in this paper.
[1]Bakshi, S.R., et al. Aluminum composite reinforced with multiwalled carbon nanotubes from plasma spraying of spray dried powders[J]. Surface and Coatings Technology, 2009, 203(10-11):1544-1554.[2]Singhal, S.K., et al. Carbon nanotubes: Amino functionalization and its application in the fabrication of Al-matrix composites[J]. Powder Technology, 2012, 215-216: 254-263.[3]Bradbury, C.R., et al. Hardness of Multi Wall Carbon Nanotubes reinforced aluminium matrix composites[J]. Journal of Alloys and Compounds, 2014, 585: 362-367.[4]Jiang, L., et al. An approach to the uniform dispersion of a high volume fraction of carbon nanotubes in aluminum powder[J]. Carbon, 2011, 49(6): 1965-1971.[5]Peng, T. and I. Chang. Mechanical alloying of multi-walled carbon nanotubes reinforced aluminum composite powder[J]. Powder Technology, 2014, 266: 7-15.[6]Maqbool, A., et al. Mechanical characterization of copper coated carbon nanotubes reinforced aluminum matrix composites[J]. Materials Characterization, 2013, 86:39-48.[7]Yang, X., et al. Synthesis of uniformly dispersed carbon nanotube reinforcement in Al powder for preparing reinforced Al composites[J]. Composites Part A: Applied Science and Manufacturing, 2011, 42(11):1833-1839.[8]Kim, S., et al. Fabrication of flexible, aligned carbon nanotube/polymer composite membranes by in-situ polymerization[J]. Journal of Membrane Science, 2014, 460:91-98.[9]Gong, S. and Z.H. Zhu.On the mechanism of piezoresistivity of carbon nanotube polymer composites[J]. Polymer, 2014, 55(16):4136-4149.[10]Gong, F., et al. Thermal transport phenomena and limitations in heterogeneous polymer composites containing carbon nanotubes and inorganic nanoparticles[J]. Carbon, 2014 78(18):305-316.[11]丁志鹏等, 碳纳米管/铝基复合材料的制备及摩擦性能研究. 浙江大学学报(工学版), 2005, 11:1811-1815.[12]曾刚等.碳纳米管增强AlSi7Mg合金的制备及力学性能[J]. 特种铸造及有色合金, 2013, 02: 170-173.[13]史娜等.碳纳米管增强铝基复合材料的力学和物理性能[J]. 北京科技大学学报, 2013, 35(1): 104-111.[14]Pérez-Bustamante, R., et al. Wear behavior in Al2024-CNTs composites synthesized by mechanical alloying[J]. Wear, 2012, 292-293: 169-175.[15]汤金金,李才巨,朱心昆. 碳纳米管增强铝基复合材料的界面研究进展[J]. 材料导报, 2012, 26(11):149-152.[16]Wu, Y. and G. Kim. Carbon nanotube reinforced aluminum composite fabricated by semi-solid powder processing[J]. Journal of Materials Processing Technology, 2011, 211(8): 1341-1347.[17]赵霞等.搅拌摩擦加工法制备碳纳米管增强铝基复合材料[J]. 复合材料学报, 2011, 28(2): 185-190.[18]张伟,吴承伟, 碳纳米管增强铝复合材料减摩耐磨性研究进展. 兵器材料科学与工程, 2014, 3:118-121.[19]Choi, H.J., S.M. Lee , D.H. Bae. Wear characteristic of aluminum-based composites containing multi-walled carbon nanotubes[J]. Wear, 2010, 270(1-2): 12-18.[20]王筱峻等. 碳纳米管增强铝基复合材料研究进展[J]. 兵器材料科学与工程, 2013, 36(6): 127-134.[21]张国定.金属基复合材料界面问题[J]. 材料研究学报, 1997, 11(6): 649-657.[22]曾美琴,欧阳柳章. 复合材料界面研究进展[J]. 中国铸造装备与技术, 2002, 06: 23-26.[23]武高辉等.金属基复合材料界面反应控制研究进展[J]. 中国材料进展, 2012, 31(7): 51-58.[24]Choi, H.J., J.H. Shin , D.H. Bae. The effect of milling conditions on microstructures and mechanical properties of Al/MWCNT composites[J]. Composites Part A: Applied Science and Manufacturing, 2012, 43(7): 1061-1072.[25]Landry, K., S. Kalogeropoulou , N. Eustathopoulos. Wettability of carbon by aluminum and aluminum alloys[J]. Materials Science & Engineering A, 1998, 254(1): 99 - 111[26]Kwon Xibo Pei, Yongxiang Zeng, Rui He, et al. Single-walled carbon nanotubes/hydroxyapatite coatingson titanium obtained by electrochemical deposition .Applied Surface Science, 2014, 295:71-80.[27]So, K.P., et al.SiC formation on carbon nanotube surface for improving wettability with aluminum[J]. Composites Science and Technology, 2013, 74: 6-13.[28]Yang, X., et al. Fabrication of carbon nanotube reinforced Al composites with well-balanced strength and ductility[J]. Journal of Alloys and Compounds, 2013, 563: 216-220.[29]范冰冰等, 碳纳米管/铝基复合材料的制备与性能[J]. 沈阳大学学报(自然科学版), 2013, 02: 128-131.[30]Wang, L., et al. A comparison study of catalytic oxidation and acid oxidation to prepare carbon nanotubes for filling with Ru nanoparticles[J]. Carbon, 201, 49(6): 2022-2032.[31]Majid, M., et al. Fabrication and mechanical properties of MWCNTs-reinforced aluminum composites by hot extrusion[J]. Rare Metals, 2012, 31(4): 372-378.[32]Deng, C., et al. Dispersion of multiwalled carbon nanotubes in aluminum powders. Rare Metals, 2009, 28(2): 175-180.[33]Liao, J.,M. Tan, Mixing of carbon nanotubes (CNTs) and aluminum powder for powder metallurgy use[J]. Powder Technology, 2011, 208(1): 42-48.[34]孙益广等. 碳纳米管增强铝基复合材料的研究现状[J]. 热加工工艺, 2012, 41(24): 137-139.[35]Q. Qun, TG Wang ,HX Fang .Process in Ti matrix composites fabricated by powder metallurgy in situ method .Powder Metallurgy Industry.2010, 5(20):42-46.[36]Lou WW, Dong YW, Jin YF, Liu JS. Synthesis and characterzation of lanthanum-incorporated hydroxyapatite coatings .Chinese Journal of Tissue Engineering Resaerch.2014, 818:1224-1229.[37]YQ Liang. Experimental study of strontium-doped brushite coating by electronchemical .Chinese PLA general hospital & Medical school PLA.2014, 5:64-68.[38]吕凝磊.掺锶生物玻璃及其与羟基磷灰石复合材料的制备及溶解性研究.中南大学[M],2014:45-51.[39]王薇,张玉梅,闫钧,等.不同掺锶浓度羟基磷灰石涂层对成骨细胞生物学行为的影响.牙体牙髓牙周病学杂志.2010, 20(2):71-75.[40]YY. You . Preparation of nano fluoridated hydroxyapitite for dental implant coatings. Chinese Journal of Practical Stomatology. 2013, 2(6):102-104.