Abstract:A novel medium-Mn automotive steel has been designed to achieve unprecedented mechanical properties with tensile yield strength above 1.0 GPa and the product of strength and elongation exceeding 60–75 GPa·%. The tensile behavior is characterized by inhomogeneous deformation, which shows an incipient yield drop effect followed by a large Lüders straining and then several Portevin-Le Chatelier bandings during work-hardening stage. The multiple work- hardening mechanisms behind the unique mechanical properties are revealed by EBSD, TEM, 3D-ATP, and in-situ DIC observations. These results indicate that the inhomogeneous martensitic transformation occurs only within the local deformation zone, and only a small amount of martensite is required for the generation and propagation of Lüders and PLC microbands, which can provide a sustainable transformation-induced plasticity (TRIP) effect prolonging to a larger strain range. Consequently, not only the microband propagation, but also its induced local phase transitions play an important role in the multiplication of mobile dislocations, both of which provide a high density of mobile dislocations to enable strong strain hardening capabilities and the resulting unique mechanical properties.
[1] 董瀚, 廉心桐, 胡春东, 等. 钢的高性能化理论与技术进展. 金属学报, 2020, 56(4), 558-582.[2] 王存宇, 常颖, 周峰峦, 等. 高强度高塑性第三代汽车钢的M3组织调控理论与技术. 金属学报, 2020, 56(4): 400-410.[3] Soleimani, M., Kalhor, A., Mirzadeh, H. Transformation-induced plasticity (TRIP) in advanced steels: a review. Materials Science and Engineering: A, 2020, 795: 140023.[4] Dai, Z., Chen, H., Ding, R., et al. Fundamentals and application of solid-state phase transformations for advanced high strength steels containing metastable retained austenite. Materials Science and Engineering: R: Reports, 2021, 143: 100590.[5] Hu, B., He, B., Cheng, G., et al. Super-high-strength and formable medium Mn steel manufactured by warm rolling process. Acta Materialia, 2019, 174: 131-141.[6] Han, J., da Silva, A. K., Ponge, D., et al. The effects of prior austenite grain boundaries and microstructural morphology on the impact toughness of intercritically annealed medium Mn steel. Acta Materialia, 2017, 122: 199-206.[7] Kumar, S., Samanta, S., Singh, S. B. An alternative quenching and partitioning (Q&P) process via spheroidization. Materials Characterization, 2022, 191: 112049.[8] Wu, X., Zhu, Y. Heterogeneous materials: a new class of materials with unprecedented mechanical properties. Materials Research Letters, 2017, 5(8): 527-532.[9] Wu, X., Zhu, Y. Gradient and lamellar heterostructures for superior mechanical properties. MRS Bulletin, 2021, 46(3): 244-249.[10] Kuzmina, M., Ponge, D., Raabe, D. Grain boundary segregation engineering and austenite reversion turn embrittlement into toughness: example of a 9 wt.% medium Mn steel. Acta Materialia, 2015, 86: 182-192.[11] Yuan, F., Yan, D., Sun, J., Zhou, et al. Ductility by shear band delocalization in the nano-layer of gradient structure. Materials Research Letters, 2019, 7(1): 12-17.[12] He, J., Yuan, F., Yang, M., et al. Exceptional tensile properties under cryogenic temperature in heterogeneous laminates induced by non-uniform martensite transformation and strain delocalization. Materials Science and Engineering: A, 2020, 791, 139780.[13] Tian, Y. Z., Bai, Y., Chen, M. C., et al. Enhanced strength and ductility in an ultrafine-grained Fe-22Mn-0.6 C austenitic steel having fully recrystallized structure. Metallurgical and Materials Transactions A, 2014, 45(12): 5300-5304.[14] Dini, G., Najafizadeh, A., Ueji, R., et al. Improved tensile properties of partially recrystallized submicron grained TWIP steel. Materials Letters, 2010, 64(1): 15-18.[15] Kim, S. H., Kim, H., Kim, N. J. Brittle intermetallic compound makes ultrastrong low-density steel with large ductility. Nature, 2015, 518(7537): 77-79.[16] Yang, M. X., Yuan, F. P., Xie, Q. G., et al. Strain hardening in Fe–16Mn–10Al–0.86 C–5Ni high specific strength steel. Acta Materialia, 2016, 109: 213-222.[17] He, B. B., Hu, B., Yen, H. W., et al. High dislocation density–induced large ductility in deformed and partitioned steels. Science, 2017, 357(6355): 1029-1032.[18] Yang, T., Zhao, Y. L., Tong, Y., et al. Multicomponent intermetallic nanoparticles and superb mechanical behaviors of complex alloys. Science, 2018, 362(6417): 933-937.[19] Gao, J., Jiang, S., Zhang, H., et al. Facile route to bulk ultrafine-grain steels for high strength and ductility. Nature, 2021, 590(7845): 262-267.[20] Gao, B., Lai, Q., Cao, Y., Hu, et al. Ultrastrong low-carbon nanosteel produced by heterostructure and interstitial mediated warm rolling. Science Advances, 2020, 6(39): eaba8169.[21] Xu, Z., Shen, X., Allam, T., et al. Austenite transformation and deformation behavior of a cold-rolled medium-Mn steel under different annealing temperatures. Materials Science and Engineering: A, 2022, 829: 142115.[22] Wang, C., Cao, W., Shi, J., et al. Deformation microstructures and strengthening mechanisms of an ultrafine grained duplex medium-Mn steel. Materials Science and Engineering: A, 2013, 562: 89-95.[23] De Cooman, B. C., Kwon, O., Chin, K. G. State-of-the-knowledge on TWIP steel. Materials Science and Technology, 2012, 28(5): 513-527.[24] Kim, J. G., Hong, S., Anjabin, N.,et al. Dynamic strain aging of twinning-induced plasticity (TWIP) steel in tensile testing and deep drawing. Materials Science and Engineering: A, 2015, 633: 136-143.[25] Cheng, S., Wang, Y. D., Choo, H., et al. An assessment of the contributing factors to the superior properties of a nanostructured steel using in situ high-energy X-ray diffraction. Acta Materialia, 2010, 58(7): 2419-2429.[26] Ma, Y., Yang, M., Jiang, P., et al. Plastic deformation mechanisms in a severely deformed Fe-Ni-Al-C alloy with superior tensile properties. Scientific Reports, 2017, 7(1): 1-10.