|
|
Effect of binder Co and Ni on the microstructure and mechanical properties of Ti(C0.7N0.3)-based cermets |
LI Chao,LI Nan,LIU Xue-quan,LIN Fei,LI Fa-chang |
(Central Iron & Steel Research Institute, Beijing 100081, China) |
|
|
Abstract Ti(C0.7N0.3)-based cermets were prepared by low pressure sintering of powder metallurgy method. The effect of Co/(Co+Ni) ratio on microstructure and mechanical properties were investigated using SEM, EDS and mechanical properties test instrument. Results show that after sintering at 1 400 ℃ for 1 h, the microstructure of Ti(C0.7N0.3)-based cermets is composed of black core, grey shell and white binder phase. When the total binder is 20% (mass percent) and Co/(Co+Ni) ratio increases from 0 to 0.6, the bending strength of the cermet gradually increases to the maximum of 2 210 MPa, and then decreases gradually; while the hardness of the cermet reaches the maximum value of 92.1 HRA and then tends to be stable and no longer changes significantly with the increase of Co/(Co+Ni) ratio.
|
Received: 03 August 2017
Published: 22 February 2019
|
|
|
|
[1] RAJABIA,GHAZALIMJ,DAUDAR.Chemical composition,microstructure and sintering temperature modifications on mechanical properties of TiC-based cermet: a review[J].Materials&Design,2015,67:95-106.[2] XUQZ,AIX,ZHAO J,et al. Effect of heating rate on the mechanical properties and microstructure of Ti(C,N)-based cermets[J]. Materials Science and Engineering: A,2015,628:281-287.[3] 羊建高,谭敦强,陈颢. 硬质合金. 长沙:中南大学出版社[M],2012:271-273.[4] 吴鹏. Ti(C,N)基金属陶瓷的强韧化及梯度结构制备技术的研究[D]. 南京:南京航空航天大学,2014.[5] 南晴.高强韧耐腐蚀Ti(C,N)基金属陶瓷的研究[D]. 长沙:中南大学粉末冶金研究院,2013.[6] A.Rajabi,M.J.Ghazali,J.Syarif,A.R.Daud.Development and application of tool wear:A review of the characterization of TiC-based cermets with different binders[J].Chemical Engineering Journal,2014,225:445-451.[7] D.I.Chun,D.Y.Kim,K.Y.Eun.Microstructural Evolution during the Sintering of TiC-Mo-Ni Cermets [J].Journal of the American Ceramic Society,1993,76(8):2049-2052.[8] 周书助. 超细Ti(CN)基金属陶瓷粉末成形性能及刀具材料的研究[D]. 长沙:中南大学,2006.[9] 瞿峻. Ti(CN)基金属陶瓷增强技术及组织和性能研究[D]. 武汉:华中科技大学,2010.[10] Vinod K. Sarin?.Comprehensive Hard Materials. 长沙:Elsevier Ltd [M].2014:160-165.[11] 张大勇,石增敏. 原始成分组成对 Ti(C,N)基金属陶瓷烧结性能的影响[J]. 粉末冶金技术,2013,30(2):83-89.[12] Z.Shi,D.Zhang,S.Chen,T.Wang.Effect of nitrogen content on microstructures and mechanical properties of Ti(C,N)-based cermets [J]. Journal of Alloys and Compounds,2013,568:68-72.[13] N.Liu,S.Chao,X.Huang.Effects of TiC/TiN addition on the microstructures and mechanical properties ofultra-fine grade Ti(C,N)-Ni cermets [J].Journal of the European Ceramic Society,2006,26(16):3861-3870.[14] Q.Yang,W.Xiong,S.Li,J.Li. Effect of partial substitution of Cr for Ni on densification behavior,microstructure evolution and mechanical properties of Ti(C,N)-Ni-based cermets [J].Journal of Alloys and Compounds,2011,509(14):4828-4834.[15] 黄培云. 粉末冶金原理. 北京:冶金工业出版社[M], 2015:307-314.[16] Vinod K. Sarin .Comprehensive Hard Materials. Elsevier Ltd [M].2014:207.[17] Ahn, S. Y., & Kang, S. Formation of core/rim structures in Ti(C, N)-WC-Ni cermets via a dissolution and precipitation process. Journal of the American Ceramic Society[J]. 2000,83:1489–1494.[18] Vinod K. Sarin .Comprehensive Hard Materials. Elsevier Ltd [M].2014:275-290.[19] P.Ettmayer,H.Kolaska,W.Lengauer. Ti(C,N) Cermets-Metallurgy and Properties[J]. Refractory Metals&Hard Materials.1995,13:343-351.[20] Vinod K. Sarin?.Comprehensive Hard Materials [M].2014:175. |
|
|
|