Preparation of Sn/C anode film for lithium batteries via electrospinning and carbothermal reduction
FENG Sheng- ya1, YU Yong- tao2, WANG Yao1, WANG Hai- ying3
1. Advanced Technology & Materials Co., Ltd., Beijing 100081, China 2. Research Institute of Jilin Petrochemical Company Petrochina, Jilin 132021, Jilin, China 3. Changshu Institute of Technology, Changshu 215500, Jiangsu, China
Abstract:A large Sn/C non- woven film with high capacity and good cycleability have been prepared by an electrospinning of a mixture solution of SnCl4 and PAN, followed by heat- treatment at high temperature. Scanning electron microscopy (SEM), and X- ray diffraction (XRD) analyses demonstrated the morphology and the structure of the Sn/C nanofibers. At first cycle, the Sn/C nanofiber delivers high charge and discharge capacities, 808. 6 and 1 329. 8 mA·h/g, respectively. After 40 cycles, the discharge capacity remains 743 mA·h/g, which is 97. 5 % of the capacity of the second cycle.
冯圣雅,于湧涛,王 瑶,王海鹰. 静电纺丝技术结合碳热还原法制备Sn/C薄膜锂电池负极材料[J]. , 2015, 22(4): 35-38.
FENG Sheng- ya, YU Yong- tao, WANG Yao, WANG Hai- ying. Preparation of Sn/C anode film for lithium batteries via electrospinning and carbothermal reduction. , 2015, 22(4): 35-38.