Research and Development
LI Guoping, LIU Zenglin, GUO Libo, CHEN Wen, HAN Wei, LUO Fenghua
A TiC high manganese steel-bonded carbide with 0.1% boron addition was fabricated by powder metallurgy techiniques using TiC as hard phase and Fe, Ni, Mo, Mn, graphite C raw powders as the binder, and effects of sintering temperature on the microstructure and properties of the alloys were carried out. Microstructure observation shows that the structure of the alloy consists of black core-gray rim ceramic particles and white metallic binder, while, the ceramic particles grow gradually and its distribution become evenly with the temperature increase. The relative density of the alloy increases firstly and then decreases with the temperature increase, subsequently, the relative density of the alloy increases monotonously with the temperature increase and reaches the maximum value 98.29%. Mechanical properties results show that the hardness, transverse rupture strength (TRS) (in the as-sintered state and heat treatment state) and impact energy (IE) of the alloy increased monotonously with the temperature increase, also, reach the maximum value 63.8HRC, 1 993 MPa/1 425 MPa and 9.3 J/cm2. The alloy densifies singnificantly when sintered from 1 320 ℃to 1 340 ℃, then, the hardness, TRS and IE of the alloy increases obviously. Subsequently, the increase rate of the hardness, TRS and IE of the alloy slow down which indicates the distinct role of B element in promoting densification. Boron element begins to volatilize and is exhausted completely at 1 420 ℃.The experimental alloy with B addition and the high manganese steel matrix are cast into a whole part, no obvious defects as cracks, impurities and pores are observed between the interfaces showing excellent interface bonding state and prospective long service life.