Abstract:CuO/graphene is in- situ prepared by the co- precipitation method using Cu(NO3)2·3H2O and graphene oxide as raw materials. The catalyst is characterized by XRD and SEM. The catalytic performance is investigated by degradating methylene blue solution under the ultraviolet light and applied electric field. The results show that graphene has enhanced the adsorption and electrical conductivity of the catalyst and the applied electric field makes a three electrode system between catalyst particles and the two electrode plates. The catalytic properties of CuO have been highly improved because of the introduction of graphene and applied electric field. Compared with pure CuO, the photocatalytic degradation of methylene blue by CuO/graphene increases from 33.23% to 91.77%, and the photo- electro catalytic degradation of methylene blue reaches 93.16%.
Chen H, Feng F, Zhong-Liang H U, et al.Preparation of uniform flower-like CuO and flower-like CuOgraphene composite and their application in lithium ion batteries[J].Transactions of Nonferrous Metals Society of China, 2012, 22(10):2523-2528
[3]
崔萌.氧化铜纳米粒子的制备与表征[J].当代化工, 2015, 44(3):497-498
[4]
Zhang X, Zhou J, Song H, et al.Butterfly effect" in CuOgraphene composite nanosheets: a small interfacial adjustment triggers big changes in electronic structure and Li-ion storage performance[J].Acs Appl Mater Interfaces, 2014, 6(19):17236-17244
Jing L, Jin J, Zhao D, et al.Tailoring CuO nanostructures for enhanced photocatalytic property[J].Journal of Colloid & Interface Science, 2012, 384(20):1-9
[7]
Zhao Y, Song X, Song Q, et al.A facile route to the synthesis copper oxidereduced graphene oxide nanocomposites and electrochemical detection of catechol organic pollutant[J].Crystengcomm, 2012, 14(20):6710-6719
Veerapandian M, Lee M H, Krishnamoorthy K, et al.Synthesis,characterization and electrochemical properties of functionalized graphene oxide[J].Carbon, 2012, 50(11):4228-4238