Abstract:The effect of heat treatment on property of 3Cr13MoCu martensitic stainless steel was studied by metallographic microscope observations, vickers hardness measurement, antibacterial test and scanning electron microscopy (SEM) observation. The results showed that after solution treatment, the steel samples have high hardness, but the antibacterial rate were lower. increase of the aging temperature, the antibacterial rate was increased, but the hardness declined. After solution at 1080 ℃ for 30 min, water cooling to room temperature + aging at 700 ℃ for 8 h, air cooling to room temperature + solution at 1000 ℃ for 5 min, oil cooling to room temperature. the stainless steel have both excellent antibacterial performance and hardness.
[1] Shuai Wang, Ke Yang, Minggang Shen, Chunguang Yang. Effect of aging on antibacterial performance of a Cu-bearing martensitic stainless steel[J]. Materials Technology, 2014, 29(5), 257. [2] 王帅,卢志江,杨春光,沈明钢,杨柯. 17-4PH 不锈钢的抗菌性能[J]. 材料研究学报, 2014,28(1):15.[3] 刘发. 3Cr13马氏体不锈钢的高温热变形行为研究[J].中国冶金,2015,25(10):38.[4] Ren Ling, Zhu J, Nan Li, et al. Differential scanning calorimetry analysis on Cu precipitation in a high Cu austenitic stainless steel[J]. Materials & Design, 2011, 32(7): 3980.[5] Hornbogen E, Glenn R C. A meta1lographic study of precipitation of copper from alpha iron[J]. Trans Met Soc AIME, 1960,218:1064.[6] Nan Li, Yang W, Liu Yongqian, et al. Antibacterial mechanism of copper-bearing antibacterial stainless steel against E. coli[J]. Journal of Materials Science and Technology, 2008, 24(2): 197.[7] 卢志江,杨春光,王帅,樊新民,杨柯.317L-Cu奥氏体抗菌不锈钢的热变形方程及其热加工图[J]. 钢铁, 2014, 49(5): 52.[8] Nan Li, Yang Ke. Study of Cu ions dissolution from Cu-bearing antibacterial stainless steel[J]. Journal of Materials Science and Technology, 2010, 26 (10): 941.[9]王帅,杨柯,任玲,南黎,沈明钢,杨春光.含铜CoCrMo钴基合金的抗菌特性研究[J].稀有金属材料与工程,2015,44(10):2496.[10] Ren Ling, Xu L, Feng W, et al. In vitro study of role of trace amount of Cu release from Cu-bearing stainless steel targeting for reduction of in-stent restenosis[J]. Journal of Materials Science: Materials in Medicine, 2012, 23(5): 1235.[11] 王帅,杨春光,徐大可,沈明钢,南黎,杨柯.热处理对3Cr13MoCu马氏体不锈钢抗菌性能的影响[J].金属学报,2014(12):1453.[12] Shuai Wang, Chunguang Yang, Ling Ren, Minggang Shen, Ke Yang. Study on antibacterial performance of Cu-bearing cobalt-based alloy[J]. Materials letters, 2014, 129(15): 88. [13] Yang Ke, Lü Man Qi. Antibacterial properties of an austenitic antibacterial stainless steel and its security forhuman body[J]. Journal of Materials Science and Technology, 2007, 23(3):333.[14] Shuai Wang, Ke Yang, Minggang Shen, Chunguang Yang. Effect of Cu content on antibacterial activity of 17-4 PH stainless steel[J]. Materials Technology, 2015, 30(B2), 115.[15Ren Ling, Nan Li, Yang Ke. Research and development of anti-infective medical materials[J]. Materials Review, 2010, 24(6): 81.[16]马立,董文卜. 热处理工艺对12%Cr铁素体不锈钢组织性能的影响[J].中国冶金,2014,24(5);25.[17]邓永瑞,许洋,赵青.固态相变[D].北京:冶金工业出版社,1996.[18]陈安忠,任娟红,王军伟,李玉峰.高温时效对铁素体不锈钢组织和性能的影响[J].中国冶金,2018,28(11):30.